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Step 5 of 17Wafer fabrication (front-end)

Oxidation

Growing a silicon-dioxide layer.

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At a glance

Inputs

  • Silicon wafer
  • Oxygen (dry) or water vapour (wet)
  • Heat
ProcessOxidation

Outputs

  • Wafer with a controlled-thickness SiO₂ layer

What is it?

Thermal growth of a silicon-dioxide (SiO₂) layer by reacting the silicon surface with oxygen or steam at high temperature.

Why is it needed?

Silicon's native oxide is one of the reasons silicon dominates electronics: SiO₂ is a stable, high-quality insulator used as gate dielectric, masking layer, and surface passivation.

How does it work?

Wafers are heated in a furnace (typically 900–1200 °C). Dry oxidation uses O₂ for thin, high-quality films; wet oxidation uses steam for faster, thicker growth.

Oxygen diffuses through the growing oxide to react at the silicon interface, consuming some silicon as the oxide thickens.

Critical parameters

  • Oxide thickness
  • Temperature
  • Ambient (dry vs wet)
  • Interface trap density

Typical defects

  • Thickness non-uniformity
  • Pinholes
  • Interface states
  • Contamination-induced charge

Equipment involved

  • Thermal oxidation / diffusion furnace
  • Rapid thermal processing (RTP) tools

Materials involved

  • Oxygen
  • High-purity water
  • Silicon

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Related research

  • High-κ gate dielectrics beyond SiO₂
  • Ultra-thin interfacial layers
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