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Chip Manufacturing · Topic 4 of 16

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Chip ManufacturingLesson 4 of 16

Oxidation

Growing a high-quality silicon dioxide layer on the wafer.

What you’ll learn

  • How thermal oxide is grown
  • Why SiO₂ is so useful
  • Where oxide is used

Why it matters

Silicon's native oxide is one of the reasons silicon won — it makes excellent insulators and gate dielectrics.

Explanation

Heating silicon in oxygen or steam grows a dense, stable silicon dioxide (SiO₂) film directly from the wafer surface. Thickness is controlled by temperature and time.

SiO₂ serves as gate dielectric, insulation between layers, and a mask against dopants — a remarkably versatile material.

Visual explanation

A thin SiO₂ layer growing on top of (and consuming a little of) the silicon surface.

Key terminology

Thermal oxidation
Growing SiO₂ by reacting silicon with oxygen/steam.
Gate dielectric
The insulator under a transistor gate.
High-k dielectric
A newer gate insulator replacing SiO₂ at small nodes.

Example

Early MOSFET gates used a few nanometres of thermal SiO₂ as the gate dielectric.

Common mistakes

Real-world application

At advanced nodes, SiO₂ gate dielectrics were replaced by high-k materials to cut leakage.

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Oxidation

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Deposition

Chip Manufacturing

Adding thin films of conductors, insulators, and semiconductors layer by layer.

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